I completely agree with Linda. This is a great model but a bad photo, especially with the light being what it is on her face. It's not worth trying to "fix" and this photo's not worth your time to paint.
If I were you I would practice everything you've learned about posing and lighting, get this gorgeous young model in front of the camera for an hour or so every week and you'll have some fantastic new reference photos for a whole portfolio of knock out portraits.
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