A couple of concerns...
1. Electricity
2. Lighting
3. Sink and water
4. Climate control - it can get darn hot and cold in those boxes. You would need a climate controlled facility.
5. Is it allowed? Most storage space owners don't have insurance or zoning to allow you to spend vast amounts of time on-site.
Surely there are better places to paint. That said, if you have no choice, it could me made to work if you can resolve the above factors.
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