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I think that the light measuring differs in the two pictures. In the girls picture it looks like the camera has measured the light on her face correct because the highlights on the left side are correct exposed and the background is underexposed.
On the boy the face is overexposed and the background is correctly exp.
The camera has measured on the background, and that is why the face is overexposed.
Do you have a spot metering in the camera? Be sure to measure at the light parts of the face.
Allan
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